ࡱ> mol{ RZA8-<E` " -<TjH r<000 . 8T`j<0 <00V6@Hg7jUHޝ-6 ;<0<6xA-Lg7g7A, L$` 8 0 -<-<.H < L , : 2020t^hQVUxXxvzubuՋRՋ}TՋ  B wS)ST{Hh yvNx 618 yv Ty e:gSf[ NUSy b(qQ10\ k\3R qQ30 R) 1-5 D A D A D 6 -10 C B A D A NkXzz(qQ20zz kzz2R qQ40R) 102 3 20x HPO42"  3011.12 9.34 40KIO3 Cl2SNbcMOn  50K2CO3 NH4HCO3  60H3BO3 H2  70x~ Ag[(NH3)2]+ 80Fe(OH)3 [Co(NH3)6]3+ 90Ni2(OH)2SO4 [Ni(NH3)6]SO4  100N 40 NMs^(qQ5\ k\4R qQ20 R) 1. 3Cl2+6NaOH(p)  EMBED Equation.3  NaClO3+5NaCl+3H2O 2. PbS + 4H2O2 !PbSO4!+ 4H2O 3. 2AgNO3(s) EMBED Equation.3 2Ag + 4NO2!+ O2! 4. S2O32- + 2H+ !SO2!+ S!+ H2O 5. 2MnO4- + SO32- + 2OH- !2MnO42- + SO42- + 2H2O V{T{qQ4\ k\5R qQ20 R 1(,g5R) T{CQ }v&{S:NCr1R SP[8hY5uP[c^_:N1s22s22p63s23p63d54s12R (WCQ }hTgh-NveS:NVIB1R @bYvR:SMOn:Nd:S1R 0 2(,g5R) T{1uNNO3"-NN5uP[[pe:N31R .5uP[[pe:N31R d[5uP[[pe:N01R @bN勻yP[vzzgW:Nck N҉b_2R 0 3,g5R T{V:NNa+ YB\5uP[:N85uP[gW YNuvgSR_\1R VdkNaCl:NxQWvyP[vfSO1R  Al3+5uwؚ NuvgSR'Y2R V AlCl3-NvSf[.+T gYvqQNbR :NRP[vfSO1R VdkvfSONaClvqpؚNAlCl30 4(,g5R) T{t2g5eg22R ckkQbSO1R ؚe2R 0 N{qQ5\ k\8R qQ40 R 1(,g8R) 1  EMBED Equation.3 (600K) = EMBED Equation.3 - T  EMBED Equation.3  1R = [-197.78  500 ( -188.06 ( 10-3] kJmol-1 = -103.75 kJmol-1 < 0 2R @bNS^(W500 KvhQr` NSTSۏL0 1R 2 rGm =  EMBED Equation.3  + RTlnJ 1R = -103.75 + 8.314 ( 500 ( ln{(2.00(103/105)2/[(2.00(103/105)2 ((2.00(103/105)]} ( 10-3 = -96.7 kJmol-1 < 0 2R @bNS^(W500K02.00(103 Pa NTSSۏL0 1R 2(,g8R) H2CO3  H+ + HCO3- 1R cmolL-1 0.10-x x x 5" c/Ka,1 >500 4" 0.10  x H" 0.10 x = (4.410"7(0.10)1/2 = 2.110-4 2R pH =  lg c( H+)/c =  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hOThOTCJOJPJQJaJhOThOTOJQJaJ#hOThOTCJOJPJQJaJo(h~h~@H*OJQJo(hRh+5OJQJaJh>`@OJQJaJo(h+5@OJQJaJo(hQh~@OJQJaJo(ha{`h~@H*OJQJh~@H*OJQJo(ha{`h~@OJQJ jha{`h~@OJQJ "$*,:@BD\dftx~ѼѬњ{n[F[4"hh9s@OJQJ]aJo((h9sh9s6@H*OJQJ]aJo(%h9sh9s6@OJQJ]aJo(hRhOJQJaJh@H*OJQJaJo(h9sh9s@H*OJQJaJ"h9sh9s@H*OJQJaJo(h9sh9s@OJQJaJo((jX h9sh9s@OJQJUaJo(h9sh9s@OJQJaJha{`h.H@OJQJaJha{`h.H@H*OJQJaJͶxccQAhh6@OJQJ]aJo("hhh9s6@OJQJ]aJ(hhh.H6@OJQJ\]aJo(+hhh.H6@H*OJQJ\]aJo((hhh9s6@H*OJQJ\]aJ%hhh9s6@OJQJ\]aJ,hhh9s6@OJQJ\]^JaJo("hhOT@OJQJ]aJo("hh9s@OJQJ]aJo(h.H@OJQJ]aJo( "$,.4@FHJrtvz°n^NA6AhOJQJaJo(hRhOJQJaJh6@OJQJ]aJo(hh@H*OJQJ\aJo("hlhh@H*OJQJ\aJhlhh@OJQJ\aJ%hhhh@H*OJQJ]aJo(hh@OJQJaJo(" jhQhh@OJQJaJha{`hh@H*OJQJaJhQ,hh@H*OJQJaJha{`hh@OJQJaJhh@OJQJ]aJo(z|ܷܨܷ܉yiYyLALh hyOJQJaJo(hRhOJQJaJhh5@OJQJ\aJo(h#\5@OJQJ\aJo(h5@OJQJ\aJo(h&@OJQJ\aJo(h3`@H*OJQJ\aJo(h3`@OJQJ\aJo("hlh9s@H*OJQJ\aJ%hlh9s6@OJQJ\]aJhlh9s@OJQJ\aJ%hhh9s6@OJQJ]aJo(ZZZZZZZ Z"Z$Z2Z4Z8ZBZVZXZ`ZbZdZfZjZlZrZДЂo]PAh9sh &@OJQJaJh.hvzOJQJaJ"hh6@H*OJQJ]aJo(%h.hvz6@H*OJQJ]aJ"h.hvz6@OJQJ]aJh &@OJQJaJo(h9sh &@H*OJQJaJha{`h &@H*OJQJaJha{`h &@OJQJaJh.hvz@OJQJaJUh#\h9s@OJQJaJo(h9sh9s@OJQJaJI{SOymTT H2CO3THCO3-vSm^:N0.05 molL-1 1R H2CO3  H+ + HCO3- cmolL-1 0.05-x x 0.05+ x 4.410"7 = x(0.05+x)/(0.05-x) 1R x = 4.410"7 1R pH =  lg c( H+)/c =  lg(4.410"7) = 6.36 1R 3,g8R : (1) $Relm!k^,{_Ylmvc(OH-) c1(OH-) = (310(17/0.3)1/2 = 10-8 molL-1 1R c2(OH-) = (2.7910(39/0.3)1/3 = 2.1010-13 molL-1 1R V:Nc2(OH-) < c1(OH-) , @bNFe(OH)3HQlm0 1R S_Fe(OH)3lm[hQe C3(OH-) = (2.7910(39/10-5)1/3 = 6.5310-12 molL-1 2R pH=2.81 1R c1(OH-) = 10-8 molL-1 pH=6.00 1R :NOyP[Ry, pH^c6R(W2.81~6.00KN0 1R 4(,g8R)  E(Ag+/Ag) = E((Ag+/Ag) + 0.0592lg[Ag+] = 0.80+ 0.0592lgKsp/0.10 =0.13 V 2R E(Cu2+/Cu)= E((Cu2+/Cu) + 0.0592/2lg[Cu2+] = 0.34 + 0.0592/2lg0.10 =0.31 V 2R 5u`l5uRREcell :NE(Cu2+/Cu)- E(Ag+/Ag)= 0.18 V 2R 5u`lS^vyP[e z_:NCu2++2Ag+2Br-=Cu+2AgBr! 2R 5(,g8R)  Ag+ + 2 S2O32"  [Ag(S2O32")2]3( 1R s^aecmolL-1 x 2x 0.10 - x 2.9(1013 = (0.1-x)/[x 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