ࡱ> z|y)` RJbjbj2d2%???8?,?2h@@"@@@BBBggggggg$$ihkLg-BA"BBBg@@+gk]k]k]B@@gk]Bgk]k]rUfTUg@@ ऑ%p? YDfgh02hfkM[kUgkUgDBBk]BBBBBgg\BBB2hBBBB;??  0 g:gSf[ 0Ջ'Y~  N0 zW,gBl W,gBlǏ,g zvf[`N Of[ucc g:gSf[vW,gi_0W,gt0W,gS^NS~TRg㉳QvR0 N0ՋelwSՋ ;`R100R e180R N0Ջ{|W b kXzz {T{bRg :gt ~T^(u V0ՋQ[SBl czĉ[ՋQ[V0͑pSv^wƋBl0 ,{Nz ~ [,gz͑p] g:gSTirv+TINSyr'` ,{N g:gSf[ N0 g:gSTirv+TINTyr'` 10 g:gSTirv+TIN 20 g:gSTirvyr'` N0 g:gSf[vxvz[a 10 g:gSf[vxvz[a 20 g:gSf[vvvTNR ,{N qQN.v^\'` N0qQN.t N0qQN.v^\'` ,{ N g:gSTirvR{| N0 cxgR{| N0 c[VR{| ,{Nz pp [,gz͑p] pp|~}T T ppv~g dSNS^S z ,{N ppv_T TR_g N0pp_ N0ppv TR_g ,{N ppv}T T N0`N`}T T N0|~}T T N0pWv}T T ,{ N ppv~g N0xSP[vBgSb__ N0.vb_b N0ppvga V0ppvga 10/g_ 20~f_ ,{V ppv'`( N0irt'`( N0Sf['`( 10'lS 20dSN 30pˆ ,{N dSNS^S z N0/lNS^S z N08nyWv3z['` ,{ Nz pp [,gz͑p] zS_gv}T T ppvSf['`( N5uRbS^S z 1uWRbS^S z ,{N ppv~g N0xSP[vSP2BgS N0.vb_b ,{N ppv_T TR_gsa N0ppv_ N0 TR_gsa ,{ N ppv}T T N0`N`}T T N0|~}T T ,{V ppv'`( N0irt'`( N0Sf['`( 10PS"lST"lSpSppv3z['` 20N5uRb 30'lSS^ 40ZTS^ ,{N ppv6RY N014l N0dSNp1dSS"l ,{mQ ppvN5uRbS^S zTMarkovnikovĉR N0N5uRbS^S z N0llĉR0xckyP[v3z['`0[He^vʑ N0SllĉR01uWWvRbS^ ,{N ppv]NegnT(u ,{Vz ppTNpp [,gz͑p] ppvN8hRb ppNppRbS^v_ Tp NppvSf['`( ,{N ppv~gT}T T N0YNpv~g0SPBgS N0ppv}T T ,{N ppv'`( N0irt'`( N0Sf['`( 10N5uRb 204lS 30'lS 40pSirvubS^(u 50؏S ,{ N ppv6RY ,{V Npp N0NppvR{|S}T T N0Nppv~g N0qQmNppvS^ 10qQmRb(1,2-Rb01,4-Rb) 20SpTb(Diels-Alder Reaction) V0qQmHe^ N0sc6RNs^ac6R sp [,gz͑p] \spvRb Ssv}T T ,{N spvR{|T}T T N0R{| N0}T T 10USsSTir 20SsSTir ,{N sppv'`( N0SNS^ N0'lSS^ N0RbS^ 10PSR"l 20RdS } 30RdSS"l ,{ N sppv~g N0sv~gT3z['` N0s]pSvQMuirvga N0spvzS_g [ f_g [,gz͑p] Kb'`RP[ R/S}T T +TN*N0N*NKb'`xSP[STir[ f_gsa ,{N Kb'`T[yV } N0Kb'`T[y'` 10Kb'` 20[yV } N0eIQ^TkeIQ^ 10eIQ^ 20keIQ^ ,{N +TN*NKb'`xSP[STir N0Fischerbq__ N0TiW_ N0gWvnx[ 10D/LgWvnx[ 20R/SgWvnx[ ,{ N +TN*NKb'`xSP[vSTir N0$N*N N TKb'`x 10[ f_gSO 20YmeSO 30^[ f_gSO N0$N*Nv TKb'`x 10QmeSO 20QmeSOTYmeSOv:S+R ,{V N+TKb'`xSP[eIQSTir N0TW N0NNpW ,{N srSTirvzSO_g p [,gz͑p] svN5uSNS^ [MOW[MOHe^vʑT^(u ,{N v~g N0xSP[vBgSb__ N0'Y. ,{N USspv TR_gT}T T N0USSNp N0NSNp N0 NSNp ,{ N USspv'`( N0irt'`( N0Sf['`( 10N5uSN 20RbS^ 30'lSS^ ,{V sSN[MOĉR N0$N{|[MOW 100[MO[MOW 20MO[MOW N0[MOHe^vʑ 10MO[MOWv[MOHe^ 20[MO[MOWv[MOHe^ N0SN[MOHe^v^(u ,{N Ysp'`NHiickelĉR N0T N0 N0T V0HiickelĉRT^|p 10HiickelĉR 20^|p ,{kQz sNirt[elv^(u [,gz͑p] qQm~gv~ysa [Vvyr_8T6es \byN"lSP[pev0\vˆRTevPT RP[yP[\ ,{N 5uxl1vN,i_ ,{N +}YIQ1UV ,{ N ~YIQ1IR N0~YIQ1V N0~Yyr_8T6e\ ,{V 8hxqQ/c"l11HNMR N0W,gwƋ N0O\=He^TSf[MOy N0\byN"lSP[pev V0\vˆRTevPT N0xI{ TTx NI{ Tv(P[ ,{N (1MS {N ,{]Nz dSNp [,gz͑p] dSNpv͑'`( dSNppTdSNpv͑Sf['`( SN1S^0SN2S^SvQq_TV } ,{N dSNp N0dSNpv~g0R{|T}T T N0dSNpv'`( 10N8hSN 20mdS^S_md:gt 30N;mlё^\vS^ 40؏SS^ ,{N dSNppNdSNp N0dSNppTdSNpvR{| N0dSNppTdSNpv'`( ,{ N N8hSNS^S z N0SN1S^ N0SN2S^ N0q_TV } ,{ASz 0Z0 [,gz͑p] qTNCQv'`( mdS^S zE10E2 Z0v'`( 0Z0v6RY ,{N N0R{|N}T T 10vR{| 20v}T T N0qTNCQv'`( 10N;mlё^\vS^x'` 20SNS^ 0 2 @ H L X ^ n p r    > @ H T V X ` d    ̙̽̐̉xxlxhsh/wu5aJo(h/wuOJQJaJo( h/wuaJ h/wuaJo(h/wuOJQJo(hsh/wu5o(hv4h/wuo(h_bOJQJo(hv4OJQJo( h_bo(h775CJ\o( h/wuo( h/wuCJo(h/wu5CJ\o($jh/wu5CJU\mHnHuh/wu5CJ$\o(*0 2 p r   . @ \ r  hVD^` TCVD^`HiVDWD2^H`igd77 tVDWD^t`^$a$pJJ $ 4 F H V d r ~ 6 F V VD^` 8sVD^` hVD^`V f r ~   * : J \ r g VDWD^g`   VD^` VD^` " * n r "@BTV  HJb<>>@FHPTfh0>ftbhsh/wu5aJo(hsh/wu5OJQJaJo( h/wuaJh/wuH*aJo(h/wuOJQJaJo( h/wuaJo(L "6DRv&Vz 8^ VD^`HWD`H g VDWD^g` 2BVdrF & F h8VD^` g VDWD^g`  VD^` *@N\jx  & F h8VD^` VD^` h8VD^` Jbt~(>`t HVD^` hVD^` h8VD^` VD^` >@FTh "0 h8VD^` & F h8VD^` VD^` hVD^` HVD^`0>LZhDNVb0<WD` WD`gds VD^`<Xr*F`br&DZh hVD^` HVD^`WD`brt|fh  (,:8::::::::;;;X;l;n;> >X>d>z>>>>>J@`@b@j@n@BBBBBB8CPCD h9aJo(hsh/wu5OJQJaJo(!hsh/wu5OJQJ\aJo(U h/wuaJh/wuH*aJo( h/wuaJo(h/wuOJQJaJo(hsh/wu5aJo(Bh ,>Zhz:.::: VD^` h8VD^` hVD^`30'lSS^ N0mdS^S zE10E2 ,{N Z N0Zv~g N0Zv'`( 10ZWv'`( 20s NvSNS^ 30'lSS^ ,{ N N0v~g 10{US 20mT N0v'`( 10NkxxvS^ 20.veˆ ,{ASNz Tn [,gz͑p] 0nvSf['`( Q,- Nqnv~gT'`( 0nv6RY N8hRbS^SvQS z ,{N 0nvR{|0 TR_gT}T T ,{N 0nv~g0irt'`(TIQ1'`( ,{ N 0nvSf['`( N0N8hRbS^ 10N"l0lxvRbS^ 20Ny 1993     PAGE  PAGE 9 ::H:V:h:~::::::::::;;,;J;X;n;;;;WD` heVD^e` heVDWD^e`gds hVD^`;;<0<L<`<~<<<<<=4=F=T=======>>.>H>T>p>x>HWD`HWD`x>z>>>>>>>(?@?J?d?r??????????@&@6@HWD`H he;VDWD^e`; KWD`Kgds^6@H@J@`@n@@@@AAA"A2ADAVApAAAAAABB4BBBPB heVDWD^e`gds^HWD`HPB^BBBBBBBBBCC"C8CPCfCpCzCCCCCCCCWD` :WD`:gds heVD^e`HWD`HCDD0D>D^DpDDDDDDDDDD EE(E:ENEbEvE heVDWD^e` heVDWD^e`gds heVD^e`HWD`HDDDDD,EjEtEvExEEEEEEEFFFFF:H^H`HbHjHHlII$J(J2J4JDJFJnJpJrJvJxJ|J~JJJJJ⣞vjhs0JUhHvjhHvU hLbo(h/wuh/wu5CJ\ h/wuo(h/wu5CJ\o(h/wu5OJQJ\aJo(hsh/wu5OJQJaJo(h/wuOJQJaJh/wuOJQJ\aJo( h/wuaJo(h/wuOJQJaJo(hsh/wu5aJo(-vExEEEEEFF(F2FGHITUVY0000000000   000@0%00@0%00@0%00@0%00@0@0@0@0@0@0%00P $$$' bDJJ,0 V 0<h::;x>6@PBCvEFHJJ&'()*+-./1J  '!!8@(  HB  C DB S  ? X !t W`a   -/8:CDOQ[]hilmst{|  "#*+248:>?BCHIOPVX[]`befijpqyz  !"(*:<ACHJOPSTYZ_`iz   !$%*+128:?ADFIKUWZ[^_dehilmxy '-.46;=ACHILMST^_lmwy}  "#/09;ACHJQR[]bdq %AHJRTZ[dfqs,/059<=AFMNWX[\bjpq|}      ! # , . 3 4 7 8 A B P Q _ ` c d l m o r t u w z | }         $ & - / 8 : ? @ C D E F L N R T X Y _ a h j p r v w z    ) * 8 9 E F b c h i o p v w         # $ ' ( ) * 1 2 5 7 ; < B E I K R S [ \ k l o p x y | }           # $ ) + / 1 G H \ ] ` a q r u v { |   !"(),->?BCHJN&),-1256;<BCIJKPaeglmrsvw~RVX\^ceikrs{|)+/1?@IJMNQR`aijrs}~-122445578:;=>VY9>):  ` l      $ % - F L M R S X Y _ i p r z * 8 2 5 7 B (JQ122445578:;=>VY m&4 * JU\cuCJPPR`;HXd122445578:;=>VYKPP,22445578:;=>VYcA:jh;@MH% yX} v\v^v`\o(sH 0^`o(0  ^`CJaJo(,{ 0^`0o(,{z \ ^ `\) \ ^ `\.N \N ^N `\. \ ^ `\)\^`\. \^`\o(sH 0 ^`o(,{z^`o(0\^`\.4\4^4`\) \ ^ `\.| \| ^| `\. \ ^ `\)\^`\. HH^H`o(,{  ^ `o(0 d d^d` o(0   ^ `o(,{z  4\4^4`\5CJo(  \ ^ `\.| \| ^| `\. \ ^ `\)\^`\. \^`\o(0 t0t^t`0o(,{z^`o(0\^`\.4\4^4`\) \ ^ `\.| \| ^| `\. \ ^ `\)\^`\. yh;MHcA:\uznR     ;>Z*      @2n d    ʲ'X2        v4L\Lb/wuHvs2{779_b@PPPPP( X@@@:UnknownGz Times New Roman5Symbol3& z Arial;[SOSimSun 1hBF'8f +{ !{ !!-!),.:;?]}    & 6"0000 0 0 00000 =@\]^([{  0 0 00000;[))2qHP?v42 zSyukaihui_o(u7b    Oh+'0   @ L X dpx γ̱ţ yukaihui Normal.dot ΢û12Microsoft Office Word@@Чv@"@b_ p{՜.+,0 X`px gnsy! )'   !"#$%&'()*+,-./012456789:;<=>?@ABCDEFGHIJKLMNOPQRSTUVWXYZ[\]^_`abcdefghjklmnoprstuvwx{Root Entry FИ%p}1Table3kWordDocument2dSummaryInformation(iDocumentSummaryInformation8qCompObjm  FMicrosoft Office Word ĵ MSWordDocWord.Document.89q